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Home Page » Categories » Thermodynamics

The universe is full of energy, but much of it is at equilibrium. At equilibrium no energy can flow, and therefore it cannot be used for work, any more than the level waters of a pond can be used to...

Arthur C. Clarke Firstborn
The universe is full of energy, but much of it is at equilibrium. At equilibrium no energy can flow, and therefore it cannot be used for work, any more than the level waters of a pond can be used to drive a water-wheel. It is on the flow of energy out of equilibrium - the small fraction of "useful" energy, "exergy" - that life depends.

So many of the properties of matter, especially when in the gaseous form, can be deduced from the hypothesis that their minute parts are in rapid motion, the velocity increasing with the temperature,...

James Clerk Maxwell The Scientific...
So many of the properties of matter, especially when in the gaseous form, can be deduced from the hypothesis that their minute parts are in rapid motion, the velocity increasing with the temperature, that the precise nature of this motion becomes a subject of rational curiosity. Etc., have shown that the relations between pressure, temperature and density in a perfect gas can be explained by supposing the particles move with uniform velocity in straight lines, striking against the sides of the containing vessel and thus producing pressure. {1860}

There are two approaches to the study of macroscopic physics. Historically the oldest approach, developed mainly in the first half of the 19th century by such men as Carnot, Clausius, William Thomson...

Franz Mandl Statistical...
There are two approaches to the study of macroscopic physics. Historically the oldest approach, developed mainly in the first half of the 19th century by such men as Carnot, Clausius, William Thomson (the later Lord Kelvin), Robert Mayer and Joule, is that of classical thermodynamics. This is based on a small number of basic principles - the laws of thermodynamics - which are deductions from and generalizations of a large body of experiments on macroscopic systems. They are phenomenological laws, justified by their success in describing macroscopic phenomena.
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