In the scene, Daemon's playful demeanor is highlighted through his slow, teasing smile as he addresses someone affectionately referred to as "Kitten." His lighthearted remark suggests a flirtatious and teasing interaction, aiming to calm the other person with humor.
On the other hand, the reaction of the person being teased reveals irritation and frustration. Referring to Daemon as "jerk-face" indicates a familiarity and perhaps a deeper connection, showing that while there's annoyance, there is also an underlying bond between the characters, contributing to the dynamics of their relationship.